diff --git a/requests/models.py b/requests/models.py
index 9dad48cec0..7e1522837f 100644
--- a/requests/models.py
+++ b/requests/models.py
@@ -965,6 +965,8 @@ def json(self, **kwargs):
                     # and the server didn't bother to tell us what codec *was*
                     # used.
                     pass
+                except JSONDecodeError as e:
+                    raise RequestsJSONDecodeError(e.msg, e.doc, e.pos)
 
         try:
             return complexjson.loads(self.text, **kwargs)
diff --git a/tests/test_lowlevel.py b/tests/test_lowlevel.py
index bb5c994ee4..9c05f661de 100644
--- a/tests/test_lowlevel.py
+++ b/tests/test_lowlevel.py
@@ -4,7 +4,6 @@
 from tests.testserver.server import Server, consume_socket_content
 
 import requests
-
 from .utils import override_environ
 
 
@@ -403,3 +402,26 @@ def response_handler(sock):
         assert r.url == f'http://{host}:{port}/final-url/#relevant-section'
 
         close_server.set()
+
+def test_json_decode_compatibility_for_alt_utf_encodings():
+
+    def response_handler(sock):
+        consume_socket_content(sock, timeout=0.5)
+        sock.send(
+            b'HTTP/1.1 200 OK\r\n'
+            b'Content-Length: 18\r\n\r\n'
+            b'\xff\xfe{\x00"\x00K0"\x00=\x00"\x00\xab0"\x00\r\n'
+        )
+
+    close_server = threading.Event()
+    server = Server(response_handler, wait_to_close_event=close_server)
+
+    with server as (host, port):
+        url = 'http://{}:{}/'.format(host, port)
+        r = requests.get(url)
+    r.encoding = None
+    with pytest.raises(requests.exceptions.JSONDecodeError) as excinfo:
+        r.json()
+    assert isinstance(excinfo.value, requests.exceptions.RequestException)
+    assert isinstance(excinfo.value, JSONDecodeError)
+    assert r.text not in str(excinfo.value)